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If this lattice constant is not equal to that of any readily available substrate then it can be achieved by growth of a suitable buffer layer. For example in the Si1_xGez/Si material system strain-balancing is achieved by growing a buffer layer with the appropriate Ge composition, i.e. Sii_ y Ge y . This is usually linearly graded from the pure silicon composition of the substrate to the required composition y. If a multilayer structure has periodicity, the above expression should be understood in terms of the single period i.e. it should be applied to the n layers constituting a single period, and the whole structure will then clearly be strain balanced. The previous derivation takes into account the difference in elastic properties of the layers (i.e. elastic stiffness constants). If the elastic constants are similar for all layers of the structure then the stain-balancing condition can be simplified by taking into account only the difference of the lattice constants (also known as the 'average lattice method') as:

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Conventions for Representing Structure See Figure 1-11 for examples of structural conventions, including:

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If the substrate is fixed and cannot be engineered, the quantum well structure itself has to be 'tailored' to match the substrate, the complexity of which depends on the number of different layers per period and the boundaries imposed by the desired application. In something like a quantum well infrared photodetector (QWIP) this could be achieved by altering the width of the thick barrier layer separating the quantum well absorbing regions, as provided the thickness of this layer is above some minimum (to limit the dark current) it's precise value is not too important. In a quantum cascade laser the injector region offers some flexibility to allow a design to be created which also satisfies the strain-balancing condition. 7.4 EFFECT ON THE BAND PROFILE OF QUANTUM WELLS The strain in epitaxial layers acts to change the crystal lattice geometry, i.e. to perturb its size and symmetry. This results in a change of the electronic structure in particular a modification of the conduction and valence band edges and therefore a corresponding shift in the energy levels. In order to give a quantitative measure of this further effect of strain, a general case of the strained crystal is considered under the framework of deformation potential theory. This section will consider the simple case of the conduction band F minimum, while more detailed analysis exploring the valence band will be presented in 10. If the strain is assumed to be small, which is the case in semiconductor quantum wells (~1%), first order perturbation theory can be used to calculate the band shift. The Hamiltonian under strain can be expressed as the sum of the unperturbed Hamiltonian (Ho) and the strain induced contribution (He),i.e.

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where the dependence of He on the strain is:

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and V is the original (unperturbed) crystal potential. From perturbation theory it follows that the energy shift due to strain can be expressed in terms of the deformation potential components representing the matrix elements of the relative band shift due to strain (the term in equation (7.42)) as:

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