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FOUR VALENCE ORBITALS OF PENTACOORDINATED STRUCTURE Two distinct structural types may be considered for the pentacoordinated metal complex: a trigonal bipyramid and a structure of C4v symmetry in which four of the ligands lie in a common plane. If the metal atom also lies in the same plane, then the structure is trivially derivable from the ML6 structure by removal of a ligand, as already described above. We describe this case and the more general case where the metal and fth ligand are out of the plane separately. All ML5 structures in their respective coordinate frames are shown in Figure 13.6. For the ``octahedral'' C4v structure, three of the valence orbitals form a nearly degenerate set at low energy. These are dxy b2 and dxzY dyz e. The fourth, nz 2 a1 , is well separated from the others because it su ers repulsive interactions with all ve ligands. Movement of the metal and apical ligand out of the plane relieves the repulsive interactions of nz 2 a1 , and it is substantially stabilized. At the same time, the degenerate

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There is also a quantum mechanical analog of eld concept in which the function of space and time is replaced by an operator at each point in space time [31] Quantum eld theory addresses the understanding of the quantum mechanical interaction of elds and elementary particles Quantum eld theory aspires to be the most fundamental of sciences When quantum eld theory is applied to the study of electromagnetism, it is called quantum electrodynamics (QED) When quantum eld theory is applied to the study of the strong interactions between quarks and between protons, neutrons, and other baryons and mesons, it is called quantum chromodynamics (QCD) QED is currently the best theory available for describing e ects of the electromagnetic force.

FIGURE 3.2. Burch interferometer testing a concave spherical mirror with a double pass through a scatter plate.

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The term quantum eld theory is used interchangeably with high-energy physics and particle physics, this based on the fact that the experimental support for this theory comes from a wide array of experiments involving high-energy beams of particles The use of QED has proven useful in describing the interaction of light with matter One of QED s key features is its gauge symmetry Gauge symmetry implies that when independent changes to local eld values are made at di erent points in space, the equations of quantum electrodynamics are not altered (symmetry is ensured only if the quantum description of a charged particle contains an electromagnetic eld with its gauge boson) The underlying mathematical calculations, however, are complex (these are carried out using Feynman diagrams that represent possible variations of interactions and provide a shorthand for precise mathematical formulation) QCD has a mathematical mechanism similar to that of QED.

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of Fig. 12.4 to the exact solution of Fig. 12.2. The apparent loss of accuracy as the number of time steps increases (i.e., with increasing n ) is due to the phenomenon of numerical dispersion [22], a topic considered in the next section in the context of the FDTD method. Of course, simulation accuracy improves as h, 0 for xed T = N , and L = Mh.

The following observations of interest are made by Roman Jackiw [463]: Our present-day theory for fundamental processes in nature (including descriptions of elementary particles and forces) is perceived to be successful: Experimental data con rms theoretical prediction, and where accurate calculations and experiments are attainable, agreement is achieved to six or seven signi cant gures No experiment has thus far contradicted our understanding of the gravitational interactions as described by Einstein s general relativity, nor of the strong nuclear interactions, nor of the electromagnetic and radioactivity-producing weak interactions that are now collected into the Glashow Weinberg Salam standard model The strong and electroweak theories make use of a quantum mechanical description, whereas classical physics su ces to account for all known gravitational phenomena The theoretical structure within which this success has been achieved is local eld theory, which o ers physicists a variety of applications.

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Local eld theory is a language with which physical processes are discussed and it provides a model for fundamental.

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